Kinetics of supramolecular crystallization of concentrated suspensions of monodispersed spherical silica particles
V.V. Serdobintseva, A.F. Danilyuk, C.V. Vosel, D.V. Kalinin
The kinetics of supramolecular crystallization o concentrated suspensions is three-dimensional and follows the Avrami-Erofeev equation: A=1–exp[–(kt)m], where m=4. The rate constant k is proportional to the probability of the appearance of a crystallization center in unit volume in unit time and the linear crystal growth rate, which is determined experimentally.
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