Инд. авторы:	Kuznetsov A.B, Kokh K.A., Kononova N.G., Shevchenko V.S., Rashchenko S.V., Lapin I.N., Svetlichnyi V.A., Uralbekov B.M., Bolatov A., Simonova E.A., Kokh A.E.
Заглавие:	Study of an smbo3-scbo3system and new smsc(bo3)2orthoborate
Библ. ссылка:	Kuznetsov A.B, Kokh K.A., Kononova N.G., Shevchenko V.S., Rashchenko S.V., Lapin I.N., Svetlichnyi V.A., Uralbekov B.M., Bolatov A., Simonova E.A., Kokh A.E. Study of an smbo3-scbo3system and new smsc(bo3)2orthoborate // Crystengcomm. - 2021. - Vol.23. - Iss. 6. - P.1482-1488. - ISSN 1466-8033.
Идентиф-ры:	DOI: 10.1039/d0ce01783c; РИНЦ: 44876594;
Реферат:	eng: A new SmSc(BO3)2compound was discovered from the study of SmBO3-ScBO3by solid-state synthesis. The obtained compound was grown from a stoichiometric melt by a spontaneous crystallization method, and crystallizes in the space groupR3̄ with the cell parameters ofa= 4.8951(6) Å andc= 16.3012(2) Å. In addition, phase equilibria in this system in the 900-1300 °C temperature range were studied by X-ray diffraction and thermal analyses, as well as special diffusion experiments.
Ключевые слова:	temperature range; Spontaneous crystallization; solid-state synthesis; diffusion experiments; Cell parameter; thermoanalysis;
Издано:	2021
Физ. хар-ка:	с.1482-1488
Цитирование:	1. Leonyuk, N. (2019) Crystals, 9, pp. 1-4. 2. Keszler, D.A. (1996) Borates for optical frequency conversion // Current Opinion in Solid State and Materials Science, 1 (2), pp. 204-211. https://www.journals.elsevier.com/current-opinion-in-solid-state-and-materials-science 3. Jacoby, M. 2017) Chem. Eng. News, 95, p. 12. 4. Chen, X., Zhang, B., Zhang, F., Wang, Y., Zhang, M., Yang, Z., Poeppelmeier, K.R., (..), Pan, S. (2018) Designing an Excellent Deep-Ultraviolet Birefringent Material for Light Polarization // Journal of the American Chemical Society, 140 (47), pp. 16311-16319. http://pubs.acs.org/journal/jacsat 5. Bian, Q., Yang, Z., Dong, L., Pan, S., Zhang, H., Wu, H., Yu, H., (..), Jing, Q. (2014) First principle assisted prediction of the birefringence values of functional inorganic borate materials // Journal of Physical Chemistry C, 118 (44), pp. 25651-25657. http://pubs.acs.org/journal/jpccck 6. Kokh, A., Simonova, E., Maillard, A., Maillard, R., Svetlichnyi, V., Andreev, Y., Kragzhda, A., (..), Kokh, K. (2016) Growth and dichroic properties of LiBa12(BO3)7F4 crystal // Crystal Research and Technology, 51 (9), pp. 530-533. http://www3.interscience.wiley.com/journal/117933211/grouphome/home.html 7. Kidyarov, B.I., Atuchin, V.V. (2010) Interrelationship "composition-structure-nonlinear optical properties" in aluminate crystals // Ferroelectrics, 397 (1), pp. 151-158. 8. Velchuri, R., Kumar, B.V., Devi, V.R., Prasad, G., Prakash, D.J., Vithal, M. (2011) Preparation and characterization of rare earth orthoborates, LnBO 3 (Ln = Tb, La, Pr, Nd, Sm, Eu, Gd, Dy, Y) and LaBO3:Gd, Tb, Eu by metathesis reaction: ESR of LaBO3:Gd and luminescence of LaBO3:Tb, Eu // Materials Research Bulletin, 46 (8), pp. 1219-1226. 9. Giesber, H., Ballato, J., Chumanov, G., Kolis, J., Dejneka, M. (2003) Spectroscopic properties of Er3+ and Eu3+ doped acentric LaBO3 and GdBO3 // Journal of Applied Physics, 93 (11), pp. 8987-8994. 10. Zhu, Q., Fan, Z., Li, S., Li, J.-G. (2020) Implanting bismuth in color-tunable emitting microspheres of (Y, Tb, Eu)BO3 to generate excitation-dependent and greatly enhanced luminescence for anti-counterfeiting applications // Journal of Asian Ceramic Societies, 8 (2), pp. 542-552. https://www.tandfonline.com/loi/tace20 11. Zhu, Q., Wang, S., Li, J.-G., Li, X., Sun, X. (2018) Spherical engineering and space-group dependent luminescence behavior of YBO3:Eu3+ red phosphors // Journal of Alloys and Compounds, 731, pp. 1069-1079. https://www.journals.elsevier.com/journal-of-alloys-and-compounds 12. Zhu, Q., Wang, S., Li, X., Sun, X., Li, J.-G. (2018) Well-dispersed (Y0.95-: XGdxEu0.05)(B(OH)4)CO3 colloidal spheres as a novel precursor for orthoborate red phosphor and the effects of Gd3+ doping on structure and luminescence // CrystEngComm, 20 (32), pp. 4546-4555. http://pubs.rsc.org/en/journals/journal/ce 13. Pan, W., Wang, P., Xu, Y., Liu, R. (2015) Electrodeposition and luminescent properties of YBO3:Eu3 + and Y3BO6:Eu3 + films // Thin Solid Films, 578, pp. 69-75. http://www.journals.elsevier.com/journal-of-the-energy-institute 14. Doi, Y., Satou, T., Hinatsu, Y. (2013) rystal structures and magnetic properties of lanthanide containing borates C LnM(BO3)2 (Ln=Y, Ho-Lu; M=Sc, Cr) // Journal of Solid State Chemistry, 206, pp. 151-157. 15. Durmanov, S.T., Kuzmin, O.V., Kuzmicheva, G.M., Kutovoi, S.A., Martynov, A.A., Nesynov, E.K., Panyutin, V.L., (..), Chizhikov, V.I. (2001) Binary rare-earth scandium borates for diode-pumped lasers // Optical Materials, 18 (2), pp. 243-284. 16. Fedorov, P.P. (2019) Morphotropism of Rare-Earth Orthoborates RBO3 // Journal of Structural Chemistry, 60 (5), pp. 679-691. http://www.kluweronline.com/issn/0022-4766 17. Kuznetsov, A.B., Kokh, K.A., Kononova, N.G., Shevchenko, V.S., Rashchenko, S.V., Ezhov, D.M., Jamous, A.Y., (..), Kokh, A.E. (2021) Polymorphism in SmSc3(BO3)4: Crystal structure, luminescent and SHG properties // Journal of Alloys and Compounds, 851, art. no. 156825. https://www.journals.elsevier.com/journal-of-alloys-and-compounds 18. Kokh, A.E., Kuznetsov, A.B., Pestryakov, E.V., Maillard, A., Maillard, R., Jobard, C., Kononova, N.G., (..), Kokh, K.A. (2017) Growth of the complex borates YxRySc2+z(BO3)4 (R = Nd, Pr, x + y + z = 2) with huntite structure // Crystal Research and Technology, 52 (8), art. no. 1600371. http://www3.interscience.wiley.com/journal/117933211/grouphome/home.html 19. Kuznetsov, A., Kokh, A., Kononova, N., Shevchenko, V., Uralbekov, B., Ezhov, D., Svetlichnyi, V., (..), Kokh, K. (2020) New scandium borates RxLayScz(BO3)4 (x+y+z=4, R=Sm, Tb): Synthesis, growth, structure and optical properties // Materials Research Bulletin, 126, art. no. 110850. http://www.sciencedirect.com/science/journal/00255408 20. Gheorghe, L., Khaled, F., Achim, A., Voicu, F., Loiseau, P., Aka, G. (2016) Czochralski Growth and Characterization of Incongruent Melting LaxGdyScz(BO3)4 (x + y + z = 4) Nonlinear Optical Crystal // Crystal Growth and Design, 16 (6), pp. 3473-3479. http://pubs.acs.org/journal/cgdefu 21. Li, W., Huang, L., Zhang, G., Ye, N. (2007) Growth and characterization of nonlinear optical crystal Lu0.66La0.95Sc2.39(BO3)4 // Journal of Crystal Growth, 307 (2), pp. 405-409. 22. Ye, N., Stone-Sundberg, J.L., Hruschka, M.A., Aka, G., Kong, W., Keszler, D.A. (2005) Nonlinear optical crystal Y xla ySc z(BO 3) 4 (x + y + z = 4) // Chemistry of Materials, 17 (10), pp. 2687-2692. 23. Sheldrick, G.M. (2008) A short history of SHELX // Acta Crystallographica Section A: Foundations of Crystallography, 64 (1), pp. 112-122. http://journals.iucr.org/a/journalhomepage.html 24. Farrugia, L.J. (2012) WinGX and ORTEP for Windows: An update // Journal of Applied Crystallography, 45 (4), pp. 849-854. 25. Keszler, D.A., Sun, H.X. (1988) Acta Crystallogr., Sect. C: Cryst. Struct. Commun., 44, pp. 1505-1507.