Инд. авторы: Borovikov A.A., Goverdovskiy V.A., Borisenko A.S., Bryanskiy N.V., Shabalin S.I
Заглавие: Composition and metal contents of ore-forming fluids of the Kalguty Mo-W(Be) deposit (Gorny Altai)
Библ. ссылка: Borovikov A.A., Goverdovskiy V.A., Borisenko A.S., Bryanskiy N.V., Shabalin S.I Composition and metal contents of ore-forming fluids of the Kalguty Mo-W(Be) deposit (Gorny Altai) // Russian Geology and Geophysics. - 2016. - Vol.57. - Iss. 4. - P.507-518. - ISSN 1068-7971. - EISSN 1878-030X.
Идентиф-ры: DOI: 10.1016/j.rgg.2016.04.001; РИНЦ: 27017398; SCOPUS: 2-s2.0-84963976710; WoS: 000375207800001;
Реферат: eng: Based on results of study of fluid inclusions, we have established the specific fluid regime of formation of the Kalguty Mo-W(Be) deposit (Gorny Altai). Using classical thermobarogeochemistry (cryo- and thermometry) and modern microprobing methods (Raman spectroscopy and LA-ICP-MS), we studied fluid inclusions in quartz of quartz-wolframite veins (ore formation stage I), specific 'quartz core' (quartz lens), and pyrite-chalcopyrite-molybdenite paragenesis (ore formation stage II). The results of study show that the quartz-wolframite veins of the Kalguty deposit formed with the participation of reduced W-Sb-bearing fluids with a salt content of up to 5.9 wt.%. Their gas phase consisted of CO2, N2, and CH4. Formation of pyrite-chalcopyrite-molybdenite mineralization involved oxidized hot (530-420 °C) fluids with the average salt content of 9.3 wt.%. Their gas phase was of high density (up to 0.55) and consisted of CO2, N2, and H2S. The pressure of the mineral-forming environment varied from 50 to 25 MPa. The fluids contained Cu, Mo, Bi, and S. The productive greisen-vein Mo-W(Be) mineralization of the Kalguty deposit resulted from the superposition of greisen molybdenite-chalcopyrite mineralization on parageneses of earlier formed quartz-wolframite veins. Oxidized metal-bearing fluids that formed the Mo mineralization of the Kalguty deposit have high contents of S and are geochemical analogs of magmatic metal-bearing ore-forming fluids of the Central Aldan porphyry Cu-Au-Mo deposits, which are genetically related to alkaline massifs. This suggests the significant influence of the mantle source on the formation of the Kalguty rare-metal ore-magmatic system. The same is evidenced from the sulfur isotope composition of chalcopyrite, molybdenite, and pyrite from ore parageneses, falling in the narrow range of δ34S‰ from -1.2 to +2.9 corresponding to the isotope composition of mantle sulfur. © 2015.
Ключевые слова: Redox potential; Mo-W deposits; Metal-bearing ore-forming fluids; Fluids inclusions;
Издано: 2016
Физ. хар-ка: с.507-518
Цитирование: 1. Annikova I.Yu. Major stages of ore formation and their relationship with magmatism at the Kalguty rare-metal-Mo-W deposit (Gorny Altai). Topical Issues of Geology and Minerageny of Southern Siberia [in Russian] 2001, 202-208. Izd. IGiL SO RAN.
2. Annikova, I.Yu., 2003. Rare-Metal Granites, Ongonites, and Elvans of the Kalguty Massif, Southern Altai (Composition, Relationship with Mineralization, and Petrogenetic Model of Formation). PhD Thesis [in Russian]. Novosibirsk.
3. Annikova I.Yu., Vladimirov A.G., Vystavnoi S.A., Zhuravlev D.Z., Kruk N.N., Lepekhina E.N., Matukov D.I., Moroz E.N., Palesskii S.V., Ponomarchuk V.A., Rudnev S.N., Sergeev S.A. U-Pb and 39Ar/40Ar dating and Sm-Nd and Pb-Pb isotopic study of the Kalguty molybdenum-tungsten ore-magmatic system, Southern Altai. Petrology 2006, 14(1):81-97.
4. Annikova I.Yu., Smirnov S.Z., Sokolova E.N., Khromykh S.V., Vladimirov A.G., Travin A.V. Evolution of magma chamber during the formation of the East Kalguty rare-metal-granitoid dike belt (Gorny Altai). Granites and the Earth's Evolution: Granites and Continental Crust. Proc. Second Int. Geol. Conf., 17-20 August 2014 [in Russian] 2014, 15-17. Izd. SO RAN, Novosibirsk.
5. Antipin V.S., Savina E.A., Mitichkin M.A. Geochemistry and formation conditions of rare-metal granites with various fluorine-bearing minerals (fluorite, topaz, and cryolite). Geochem. Int. 2006, 44(10):965-975.
6. Baklakov M.S. The Kalguty Mo-W deposit in Gorny Altai. Sovetskaya Geologiya 1945, 8:43-50.
7. Borisenko A.S. Analysis of the salt composition of solutions of gas-liquid inclusions in minerals by the freezing methods. Application of Thermobarogeochemical Methods to the Search for and Exploration of Ore Deposits [in Russian] 1982, 37-47. Nedra, Moscow.
8. Borisenko A.S., Borovikov A.A. Native sulfur in fluid inclusions in quartz of ore veins of the Kalguty deposi. Proceedings of the 15th Russian Conference on Thermobarogeochemistry (Moscow, Institute of Geology of Ore Deposits, Petrography, Mineralogy and Geochemistry, 18-20 September 2012) [in Russian] 2012, 16-18. IGEM RAN, Moscow.
9. Borisenko A.S., Skurydin V.A., Lebedev V.I., Obolenskaya R.V., Berezikov Yu.K., Goverdovskii V.A. Metallogeny of the ore district in southeastern Gorny Altai and northwestern Mongolia. The Regularities of Localization of Mineral Resources (Metallogeny of Siberia) [in Russian] 1988, 15:131-138. Nauka, Moscow.
10. Borisenko A.S., Obolensky A.A., Goverdovskii V.A., Ponomarchuk V.A. Age stages of formation of rare-metal mineralization in Western Mongolia and southeastern Altai. Geodynamic Evolution of Lithosphere of the Central Asian Mobile Belt (from Ocean to Continent). Proceedings of Scientific Workshop on the Program of Fundamental Research (Irkutsk, 19-22 October, 2004) [in Russian] 2004, 2:43-47. Izd. IG SO RAN, Irkutsk.
11. Borisenko A.S., Borovikov A.A., Reif F.G. Analysis of fluid inclusions using modern techniques and problems of data interpretation. Metallogeny of the Pacific Northwest: Tectonics, Magmatism and Metallogeny of Active Continental Margins: Proceedings of the Interim IAGOD Conference, Vladivostok, 1-20 September 2004 2004, 281-283. Dalnauka, Vladivostok.
12. Borisenko A.S., Vladimirov A.G., Goverdovskiy V.A., Obolenskiy A.A., Travin A.V. Geological structure, magmatism and metallogeny of Altai. Magmatism and Metallogeny of the Altai and Adjacent Large Igneous Provinces with an Introductory Essay on the Altaids. IAGOD Guidebook Series 16 2007, 9-18. CERCAMS/NHM, London.
13. Borisenko A.S., Borovikov A.A., Borisenko I.D., Bortnikov N.S., Prokofiev V.Yu., Vikent'eva O.V., Gamyanin G.N., Gaskov I.V. Sulfur forms in the hydrothermal fluids and their role in ore formation. European Current Research On Fluid Inclusions (ECROFI-XXIII), Leeds, UK, 27-29 June, 2015. Extended Abstracts Volume. http://www. see.leeds.ac.uk/research/igt/working-groups/ecrofi-conference/ 2015.
14. Borovikov A.A., Borisenko A.S. Native sulphur in fluid inclusions from quartz ore veins of the W-Mo Kalguta deposit. Fourth Biennial Conference on Asian Current Research on Fluid Inclusions. ACROFI IV (Brisbane, Australia, 10-12 August 2012). Abstracts. Brisbane 2012, 9-11.
15. Borovikov A.A., Borisenko A.S., Borisenko I.D., Gas'kov I.V. Sulfur species in hydrothermal fluids and their role in ore formation. Proceedings of the 16th Russian Conference on Thermobarogeochemistry [in Russian] 2014, 10-11. IGKh SO RAN, Irkutsk.
16. Borovikov A.A., Borisenko A.S., Gaskov I.V., Borisenko I.D., Doroshkevich A.G., Vladykin N.V., Prokopiev I.R. Composition and metal-bearing capacity of the ore-forming fluids of the Late Mesozoic alkaline complexes in the Aldan shield (Russia). European Current Research on Fluid Inclusions (ECROFI-XXIII), Leeds, UK, 27-29 June, 2015. Extended Abstracts Volume. http:.www.see.leeds.ac.uk/research/igt/working-groups/ecrofi-conference/ 2015.
17. Dashkevich E.G., Mortsev N.K., Borovikov A.A. Explosive breccias at the Kalguty deposit (Gorny Altai). Petrology, Geochemistry, and Ore Potential of Intrusive Complexes of Southern Siberia [in Russian] 1991, 44-49. Izd. OIGGM SO AN SSSR, Novosibirsk. V.I. Sotnikov (Ed.).
18. Dashkevich E.G., Borovikov A.A., Borisenko A.S., Gas'kov I.V. Composition of highly concentrated fluid inclusions in quartz from ore veins of the Samolazovskoe deposit (Central Aldan). Proceedings of the 15th Russian Conference on Thermobarogeochemistry (Moscow, Institute of Geology of Ore Deposits, Petrography, Mineralogy and Geochemistry, 18-20 September 2012) [in Russian] 2012, 31-32. IGEM RAN, Moscow.
19. Dergachev V.B. New variety of ongonites. Dokl. Akad. Nauk SSSR 1988, 302(1):188-191.
20. Dergachev V.B. Two types of ongonites and elvans. Dokl. Akad. Nauk SSSR 1989, 306(5):1216-1219.
21. Dergachev V.B. Association of subalkalic rare-metal granitoids with ongonites and elvans. Dokl. Akad. Nauk SSSR 1990, 311(4):959-962.
22. Dergachev V.B., Nikitina E.I. Contents of water and carbon dioxide and the kinetics of their release from quartz of tungsten deposits in southeastern Gorny Altai. Mineralogy and Petrography of Rocks and Ores of Major Siberian Ore Districts [in Russian] 1983, 18-27. Nauka, Novosibirsk.
23. Dergachev V.B., Timofeev N.I., Ladygina I.N. Zonation of the Kalguty Mo-W deposit. Zonation of Siberian Ore Deposits [in Russian] 1981, 289:84-91. SNIIGGiMS, Novosibirsk.
24. Ermakov N.P. Geochemical Systems of Inclusions in Minerals [in Russian] 1972, Nedra, Moscow.
25. Friedman I., O'Neil J.R. Compilation of stable isotope fractionation factors of geochemical interest. Data of Geochemistry (6th ed.). Geol. Surv. Prof. Pap. U.S., 440-KK 1977, 1-12. M. Fleischer (Ed.).
26. Gonevchuk V.G., Gonevchuk G.A., Korostelev P.G., Semenyak B.I., Seltmann R. Tin deposits of the Sikhote-Alin and adjacent areas (Russian Far East) and their magmatic association. Austral. J. Earth Sci. 2010, 57:777-802.
27. Goverdovskiy V.A. Geologic location and types of tungsten mineralization in Gorny Altai and adjacent areas of Tyva and Mongolia. Natural Resources of Gorny Altai [in Russian] 1997, 86-109. Univer-Print, Gorno-Altaisk.
28. Goverdovskiy V.A., Borisenko A.S., Obolensky A.A., Ponomarchuk V.A., Babich V.V. Geodynamic settings and age borders of formation of rare-metal mineralization in Western Mongolia. Prirodnye Resyrsy Altaya 2005, 1:63-67.
29. Graupner T., Kempe U., Dombon E., Pätzold O., Leeder O., Spooner E.T.C. Fluid regime and ore formation in the tungsten(- yttrium) deposits of Kyzyltau (Mongolian Altai): evidence for fluid variability in tungsten-tin ore systems. Chem. Geol. 1999, 154:21-58.
30. Gusev N.I. Chronology (SHRIMP II) of magmatism in the Kalguty rare-metal-tungsten-molybdenum ore-magmatic system, Gorny Altai, Russia. Geol. Ore Deposits 2011, 53(3):248-263.
31. Gusev N.I., Gusev A.I., Shokal'skii S.P., Kashin S.V., Krupchatnikov V.I., Ponomarev A.L. Magmatism and porphyry Mo mineralization of the Kalguty ore field (Gorny Altai). Regional'naya Geologiya i Metallogeniya 2010, 43:83-97.
32. Ivanova G.F., Maksimyuk I.E., Shuvalov I.G., Bessonenko V.V., Borovikov A.A. Mineralogical and geochemical characteristics of wolframite mineralization of Western Mongolia. Geologiya Rudnykh Mestorozhdenii 1988, 30(4):17-29.
33. Ivanova G.F., Kolesov G.M., Karpukhina V.S., Cherkasova E.V. Rare-earth elements and the genesis of ore mineralization at the Kalgutinskoe tungsten ore field. Gornyi Altai. Geochem. Int. 2006, 44(5):508-515.
34. Khodanovich P.Yu. Molybdenum-tungsten deposits of the Dzhida ore field. Deposits in Transbaikalia [in Russian] 1995, 1, Book 1:149-163. Geoinformmark, Moscow.
35. Kirgintsev A.N., Trushnikova L.N., Lavrent'eva V.G. Water Solubility of Inorganic Substances. A Reference-Book [in Russian] 1972, Leningrad, Khimiya.
36. Kozlov V.D., Sandimirova G.P., Pakhol'chenko Yu.A., Kalmychkova T.N., Ignatov V.V., Al'mukhamedov E.A. On Mesozoic age of ore-bearing granites of the Kyzyl-Tau Massif (Mongolian Altay). Geologiya i Geofizika (Russian Geology and Geophysics) 1995, 36(3):73-77. (65-70).
37. Kuzhel'naya E.V., Dergachev V.B. Vertical zonality of tungsten deposits at various depths in Gorny Altai. Geologiya i Geofizika (Russian Geology and Geophysics) 1990, 31(5):59-67. (56-63).
38. Luzgin B.N. Spatial model of mineralization of the Kalguty ore district (Gorny Altai). Sovetskaya Geologiya 1988, 8:94-97.
39. Landtwing M.R., Pettke T., Halter W.E., Heinricha C.A., Redmond P.B., Einaudi M.T., Kunzec K. Copper deposition during quartz dissolution by cooling magmatic-hydrothermal fluids: The Bingham porphyry. Earth Planet. Sci. Lett. 2005, 235:229-243.
40. Morozov O.A. K-Ar dating of objects of different phases from the Kalguty granite massif (Gorny Altai). Izv. AN SSSR. Ser. Geol. 1986, 10:145-149.
41. Morozov, O.A., 1986b. Geologic Structure and Stages of Formation of the Kalguty Mo-Rare-Metal-W Ore Field (Gorny Altai). PhD Thesis [in Russian]. Moscow.
42. Morozov O.A., Mel'nikova K.M., Kryukov V.K. Structure of the Kalguty granite massif (Gorny Altai). Izv. AN SSSR. Ser. Geol. 1984, 10:106-112.
43. Potseluev A.A., Babkin D.I., Kotegov V.I. The Kalguty complex deposit, the Gorny Altai: mineralogical and geochemical characteristics and fluid regime of ore formation. Geol. Ore Deposits 2006, 48(5):384-401.
44. Potseluev A.A., Babkin D.I., Koz'menko O.A. Metals in fluid inclusions of greisen deposits (Kalguty deposit). Izvestiya Tomskogo Politekhnicheskogo Universiteta 2006, 309(5):26-32.
45. Potseluev A.A., Rikhvanov L.P., Vladimirov A.G., Annikova I.Yu., Babkin D.I., Nikiforov A.Yu., Kotegov V.I. Kalguty Rare-Metal Deposit (Gorny Altai): Magmatism and Ore Genesis [in Russian]. STT, Tomsk 2008, 4.
46. Roedder E. Fluid Inclusions. Reviews in Mineralogy 1984, 12. Mineral. Soc. Am, Washington, D.C.
47. Rodionov S.M., Schnaider A.A., Romanovsky N.P., Gurovich V.G. Molybdenum mineralization in the ores of the Tigriny tin deposit (Primorye, Russia). Geol. Ore Deposits 2007, 49(4):285-296.
48. Sobotovich E.V., Bartnitskii E.N., Ts'on' O.V., Kononenko L.V. Reference-Book on Isotope Geochemistry [in Russian] 1982, Energoizdat, Moscow.
49. Sokolova, E.N., 2014. Physicochemical Conditions of Crystallization of Granite Melts in Rare-Metal Dike Belts of Southern Altai and Eastern Kazakhstan. PhD Thesis [in Russian]. OIGGM SO RAN, Novosibirsk.
50. Sokolova E.N., Smirnov S.Z. Crystallization of P-rich minerals from the high phosphorus rare-metal magma of East-Kalguty dyke belt (S. Altay, Russia). Goldschmidt Abstracts-2013 (Florence, Italy, 25-30 August 2013) 2013, 77 (5):2232. Mineral. Mag.
51. Sokolova E.N., Smirnov S.Z., Astrelina E.I., Annikova I.Yu., Vladimirov A.G., Kotler P.D. Ongonite-elvan magmas of the Kalguty ore-magmatic system (Gorny Altai): composition, fluid regime, and genesis. Russian Geology and Geophysics (Geologiya i Geofizika) 2011, 52(11):1378-1400. (1748-1775).
52. Sotnikov V.I., Nikitina E.I. Molybdenum-rare-metal-tungsten (greisen) association of Gorny Altai. Endogenous Ore Associations of Siberia [in Russian] 1971, Nauka, Novosibirsk.
53. Sotnikov V.I., Berzina A.P., Nikitina E.I., Proskuryakov A.A., Skuridin V.A. Copper-Molybdenum Ore Association (by the Example of Siberia and Adjacent Regions) [in Russian] 1977, Nauka, Novosibirsk.
54. Sourirajan S., Kennedy G.C. The system H2O-NaCl at elevated temperatures and pressures. Am. J. Sci. 1962, 260:115-141.
55. Ulrich T., Günther D. The evolution of a porphyry Cu-Au deposit, based on LA-ICP-MS analysis of fluid inclusions: Bajo de la Alumbrera. Argentina. Econ. Geol. 2001, 96:1743-1774.
56. Stel'machenok, K.Z., 1995. Conditions and Factors of Formation of Mo-W Stockwork Mineralization (by the Example of Deposits of the Dzhida Ore Cluster). PhD Thesis [in Russian]. Ulan-Ude.
57. Vladimirov A.G., Vystavnoi S.A., Titov A.V., Rudnev S.N., Dergachev V.B., Annikova I.Yu., Tikunov Yu.V. Petrology of Early Mesozoic rare-metal granites of Southern Gorny Altai. Geologiya i Geofizika (Russian Geology and Geophysics) 1998, 39(7):901-916. (909-924).
58. Vladimirov A.G., Kozlov M.S., Shokal'skii S.P., Khalilov V.A., Rudnev S.N., Kruk N.N., Vystavnoi S.A., Borisov S.M., Berezikov Yu.K., Metsner A.N., Babin G.A., Mamlin A.N., Murzin O.M., Nazarov G.V., Makarov V.A. Major epochs of intrusive magmatism of Kuznetsk Alatau, Altai, and Kalba (from U-Pb isotope dates). Geologiya i Geofizika (Russian Geology and Geophysics) 2001, 42(8):1157-1178. (1089-1109).
59. Vladimirov A.G., Annikova I.Yu., Antipin V.S. Ongonite-elvan magmatism of southern Siberia. Litosfera 2007, 4:21-40.
60. White, W.H., Bookstrom, A.A., Kamilli, R.J., Ganster, M.W., Smith, R.P., Ranta, D.E., Steininger, R.C., 1981. Character and origin of Climax-type molybdenum deposits. Econ. Geol. 75th Anniv. Vol., 270-316.
61. Wallace S.R., Muncaster N.K., Jonson D.C., MacKenzie W.B., Bookstrom A.A., Surface V.E. Multiple intrusion and mineralization at Climax, Colorado. Ore Deposits of the United States 1933-1967 1968, 603-640. American Institute of Mining, Metallurgical, and Petroleum Engineers, New York. J.D. Ridge (Ed.).