Инд. авторы:	Palyanov Y.N., Kupriyanov I.N., Borzdov Y.M., Nechaev D.V.
Заглавие:	Effect of the solvent-catalyst composition on diamond crystallization in the Mg-Ge-C system
Библ. ссылка:	Palyanov Y.N., Kupriyanov I.N., Borzdov Y.M., Nechaev D.V. Effect of the solvent-catalyst composition on diamond crystallization in the Mg-Ge-C system // Diamond and Related Materials. - 2018. - Vol.89. - P.1-9.
Идентиф-ры:	DOI: 10.1016/j.diamond.2018.08.002; РИНЦ: 35754049; SCOPUS: 2-s2.0-85050976859; WoS: 000449240000001;
Реферат:	eng: Crystallization of diamond in the Mg-Ge-C system has been studied at 7.5 GPa and 1800 degrees C with the catalyst composition ranging from pure Mg to pure Ge. It is found that with increasing Ge content of the solvent-catalyst, the degree of graphite-to-diamond conversion gradually decreases from 92 to 16%, which is a consequence of the low solubility of carbon in the germanium melt. A decrease in the Mg/Ge ratio leads to a change in the diamond growth form from cube to octahedron and a drastic increase in the number of diamond nucleation centers. The spectral properties of the crystallized diamonds are studied by photoluminescence techniques. The correlations between the Ge content of the Mg-Ge-C system and the luminescence characteristics of the diamond crystals caused by the germanium-vacancy, silicon-vacancy, and nitrogen-vacancy optical centers are established. The results obtained in this study demonstrate that by changing the catalyst composition in the Mg-Ge-C system, it is possible to control the design of the diamond crystals and synthesize isometric, pyramidal, prismatic or needle-like crystals containing Ge-V centers.
Ключевые слова:	CENTERS; DEFECTS; MORPHOLOGY; HIGH-PRESSURE; VACANCY COLOR-CENTER; Impurities; Defect characterization; Solvent-catalysts; High pressure high temperature (HPHT); Synthetic diamond; Optical properties; SPINS;
Издано:	2018
Физ. хар-ка:	с.1-9
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