Инд. авторы: | Moshkina E., Seryotkin Y., Bovina A., Molokeev M., Eremin E., Belskaya N., Bezmaternykh L. |
Заглавие: | Crystal formation of Cu-Mn-containing oxides and oxyborates in bismuth-boron fluxes diluted by MoO3 and Na2CO3 |
Библ. ссылка: | Moshkina E., Seryotkin Y., Bovina A., Molokeev M., Eremin E., Belskaya N., Bezmaternykh L. Crystal formation of Cu-Mn-containing oxides and oxyborates in bismuth-boron fluxes diluted by MoO3 and Na2CO3 // Journal of Crystal Growth. - 2018. - Vol.503. - P.1-8. - ISSN 0022-0248. - EISSN 1873-5002. |
Идентиф-ры: | DOI: 10.1016/j.jcrysgro.2018.09.011; РИНЦ: 35731535; SCOPUS: 2-s2.0-85053797039; WoS: 000446880400001; |
Реферат: | eng: The high-temperature crystallizing phases of fluxes (molten solutions) based on Bi2O3:MoO3 = 1:3 and diluted by Na2CO3 and B2O3 (under varying of Na2CO3:B2O3), and by CuO and Mn2O3 (0 <= Mn2O3:CuO <= 5) are studied. The conditions of the stable crystallization of Mn1-x2+CuxMoO4, Mn23+O3, Mn2+Mn23+O4, Mn1-x2+CuxMn3+BO4 and Mn2-x2+CuxMn3+BO5 have been found. The influence of MoO3 and Na2CO3 to the crystallization processes of Mn2+ - and Mn3+ -containing Mn1-x2+CuxMoO4 and Mn2+Mn23+O4 and Mn23+O3 are clarified. The occurrence of the chemical bonds of these types at the crystallization of Mn-heterovalent Mn1-x2+CuxMn3+BO4 and Mn2-x2+CuxMn3+BO5 oxyborates is studied. Single crystal growth techniques of these oxyborates are suggested. The results of the structural and magnetic characterization of some discussed compounds are presented. |
Ключевые слова: | LUDWIGITE; GROWTH; SINGLE-CRYSTALS; Manganites; Single crystal growth; Growth from solutions; Characterization; Magnetic materials; MAGNETISM; |
Издано: | 2018 |
Физ. хар-ка: | с.1-8 |
Цитирование: | 1. Bugaris, Daniel E., zur Loye, Hans-Conrad, Materials discovery by flux crystal growth: quaternary and higher order oxides. Angew. Chem. Int. Ed. 51 (2012), 3780–3811. 2. Jia, Zhen, Zhang, Ningning, Ma, Yingying, Zhao, Liwei, Xia, Mingjun, Li, Rukang, Top-seeded solution growth and optical properties of deep-uv birefringent crystal Ba 3. Görnert, P., Kinetics and mechanism of flux crystal growth. Prog. Cryst. Growth Charact. 20 (1990), 263–284. 4. Zhang, Weiguo, Tao, Xutang, Zhang, Chengqian, Gao, Zeliang, Zhang, Yongzhuan, Wentao, Yu, Cheng, Xiufeng, Liu, Xuesong, Jiang, Minhua, Bulk growth and characterization of a novel nonlinear optical crystal BaTeMo 5. Pollert, E., Netřiva, M., Durčok, S., Growth of single crystal materials from high temperature solutions. Prog. Cryst. Growth Charact. 22 (1991), 143–182. 6. Valery, I., Chani, Shimamura, Kiyoshi, Young, M.Yu., Fukuda, Tsuguo, Design of new oxide crystals with improved structural stability. Mater. Sci. Eng. R20 (1997), 281–338. 7. Leonyuk, N.I., Leonyuk, L.I., Growth and characterization of RM 8. Gudim, I.A., Eremin, E.V., Temerov, V.L., Flux growth and spin reorientation in trigonal Nd 9. Huang, Min, Zhang, Shouye, Growth and characterization of rare-earth iron garnet single crystals modified by bismuth and ytterbium substituted for yttrium. Mater. Chem. Phys. 73 (2002), 314–317. 10. Pachauri, Neha, Khodadadi, Behrouz, Althammer, Matthias, Singh, Amit V., Loukya, B., Datta, Ranjan, Iliev, Milko, Bezmaternykh, Leonard, Gudim, Irina, Mewes, Tim, Gupta, Arunava, Study of structural and ferromagnetic resonance properties of spinel lithium ferrite (LiFe 11. Demidov, A.A., Volkov, D.V., Gudim, I.A., Eremin, E.V., Boldyrev, K.N., Magnetic, magnetoelastic, and spectroscopic properties of TmAl 12. Moshkina, Evgeniya, Krylov, Alexander, Sofronova, Svetlana, Gudim, Irina, Temerov, Vladislav, Crystal Growth and Raman Spectroscopy Study of Sm 13. Terayama, Kiyoshi, Ikeda, Masao, Study on thermal decomposition of MnO 14. Van Uiter, L.G., Rubin, J.J., Bonner, W.A., Preparation of single crystals of tungstates and molybdates of a number of divalent metal ions. J. American Ceramic Soc. –Discussions Notes, 46(10), 1963, 512. 15. Bezmaternykh, L.N., Kolesnikova, E.M., Eremin, E.V., Sofronova, S.N., Volkov, N.V., Molokeev, M.S., Magnetization pole reversal of ferrimagnetic ludwigites Mn 16. Sofronova, S.N., Bezmaternykh, L.N., Eremin, E.V., Nazarenko, I.I., Volkov, N.V., Kartashev, A.V., Moshkina, E.M., The superexchange interactions and magnetic ordering in low-dimentional ludwigite Ni 17. Moshkina, Evgeniya, Ritter, Clemens, Eremin, Evgeniy, Sofronova, Svetlana, Kartashev, Andrey, Dubrovskiy, Andrey, Bezmaternyk, Leonard, Magnetic structure of Cu 18. Moshkina, E.M., Platunov, M.S., Seryotkin, Yu.V., Bovina, A.F., Eremin, E.V., Sofronova, S.N., Bezmaternykh, L.N., Transformation of structure and magnetic properties of Cu 19. Sofronova, Svetlana, Moshkina, Evgeniya, Nazarenko, Ilya, Veligzhanin, Alexey, Molokeev, Maxim, Eremin, Evgeniy, Bezmaternykh, Leonard, Chemical disorder reinforces magnetic order in ludwigite (Ni, Mn) 20. Norrestam, R., Kritikos, M., Sjödin, A., Manganese (II, III) oxyborate, Mn 21. Bruker AXS TOPAS V4: General profile and structure analysis software for powder diffraction data. – User's Manual. Bruker AXS, Karlsruhe, Germany. 2008. 22. Sheldrick, G.M., A short history of SHELX. Acta Cryst. A. 64 (2008), 112–122. 23. Bezmaternykh, Leonard, Evgeniya Moshkina, Evgeniy Eremin, Maxim Molokeev, Nikita Volkov, Yurii Seryotkin, Spin-lattice coupling and peculiarities of magnetic behavior of ferrimagnetic ludwigites Mn 2+M 2+Mn3+BO 24. Kazak, N.V., Platunov, M.S., Knyazev, Yu.V., Ivanova, N.B., Bayukov, O.A., Vasiliev, A.D., Bezmaternykh, L.N., Nizhankovskii, V.I., Gavrilkin, S.Yu., Lamonova, K.V., Ovchinnikov, S.G., Uniaxial anisotropy and low-temperature antiferromagnetism of Mn 25. Moshkina, Evgeniya, Sofronova, Svetlana, Veligzhanin, Alexey, Molokeev, Maxim, Nazarenko, Ilya, Eremin, Evgeniy, Leonard Bezmaternykh. Magnetism and structure of Ni 26. Platunov, M.S., Kazak, N.V., Knyazev, Yu.V., Bezmaternykh, L.N., Moshkina, E.M., Trigub, A.L., Veligzhanin, A.A., Zubavichus, Y.V., Solovyov, L.A., Velikanov, D.A., Ovchinnikov, S.G., Effect of Fe-substitution on the structure and magnetism of single crystals Mn |