| Инд. авторы: | Shatskiy A., Podborodnikov I.V., Arefiev A.V., Minin D.A., Chanyshev A.D., Litasov K.D. |
| Заглавие: | Revision of the CaCO3-MgCO3 phase diagram at 3 and 6 GPa |
| Библ. ссылка: | Shatskiy A., Podborodnikov I.V., Arefiev A.V., Minin D.A., Chanyshev A.D., Litasov K.D. Revision of the CaCO3-MgCO3 phase diagram at 3 and 6 GPa // American Mineralogist. - 2018. - Vol.103. - Iss. 3. - P.441-452. - ISSN 0003-004X. - EISSN 1945-3027. |
| Идентиф-ры: | DOI: 10.2138/am-2018-6277; РИНЦ: 35520008; SCOPUS: 2-s2.0-85043274852; WoS: 000431121100011; |
| Реферат: | eng: Subsolidus and melting relationships for the system CaCO3-MgCO3 have been reexamined using a Kawai-type multi-anvil apparatus at 3 and 6 GPa in graphite capsules. Phase boundaries were delineated according to the chemical composition of phases measured by electron microprobe in energy dispersive mode and identification of crystal phases by Raman spectroscopy. At 3 GPa, the dolomite-magnesite solvus intersects the melting loop at about 1250 degrees C, and the isothermal three-phase line so produced represents the peritectic reaction: dolomite (Ca# 43) = magnesite (Ca# 13) + liquid (Ca# 48), where Ca# = 100.Ca/(Ca+Mg). The melting loop for the CaCO3-MgCO3 join extends from 1515 degrees C (CaCO3) to 1515 degrees C (MgCO3) through a liquidus minimum at 1230 degrees C (near 53 mol% CaCO3). Starting from 1425 degrees C at = 30 mol% CaCO3 in the system, the liquid quenches to dendritic carbonate and periclase and contains rounded voids, indicating an incongruent melting reaction: MgCO3 (magnesite) = MgO (in liquid) + CO2 (fluid and/or liquid). At 6 GPa, aragonite + magnesite assemblage is stable up to 1000 degrees C. The reaction aragonite + magnesite = dolomite locates between 1000 and 1050 degrees C. The presence of dolomite splits the system into two partial binaries: aragonite + dolomite and dolomite + magnesite. The dolomite-magnesite solvus intersects the melting loop between 1400 and 1450 degrees C, and the isothermal three-phase line so produced represents the peritectic reaction: dolomite (Ca# 31) = magnesite (Ca# 21) + liquid (Ca# 57). The melting loop for the CaCO3-MgCO3 join extends from 1660 degrees C (CaCO3) to 1780 degrees C (MgCO3) through a liquidus minimum at 1400 degrees C and 62 mol% CaCO3. The compositions of carbonate crystals and melts from the experiments in the carbonated eclogite (Yaxley and Brey 2004) and peridotite (Dalton and Presnall 1998) systems are consistent with the geometry of the CaCO3-MgCO3 melting loop at 3 and 6 GPa: Ca-dolomite melt coexists with Mg-calcite in eclogite and peridotite at 3 GPa and dolomite melt coexists with magnesite in peridotite at 6 GPa. |
| Ключевые слова: | high-pressure; magnesite; dolomite; calcite; KIMBERLITE PIPE; BEARING ECLOGITE; CaCO3-MgCO3; CARBONATED PELITES; PERIDOTITE XENOLITHS; MELTING RELATIONSHIPS; UPPER-MANTLE; MINERAL INCLUSIONS; LIQUID IMMISCIBILITY; HIGH-PRESSURE; Earth's mantle; aragonite; JOIN CACO3-MGCO3; phase relations; |
| Издано: | 2018 |
| Физ. хар-ка: | с.441-452 |
| Цитирование: | 1. Akella, J., and Kennedy, G.C. (1971) Melting of gold, silver, and copper - Proposal for a new high-pressure calibration scale. Journal of Physical Research, 76, 4969-4977.
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