Инд. авторы:	Leonova G.A., Mal'tsev A.E., Melenevskii V.N., Miroshnichenko L.V., Kondrat'eva L.M., Bobrov V.A.
Заглавие:	Geochemistry of Diagenesis of Organogenic Sediments: An Example of Small Lakes in Southern West Siberia and Western Baikal Area
Библ. ссылка:	Leonova G.A., Mal'tsev A.E., Melenevskii V.N., Miroshnichenko L.V., Kondrat'eva L.M., Bobrov V.A. Geochemistry of Diagenesis of Organogenic Sediments: An Example of Small Lakes in Southern West Siberia and Western Baikal Area // Geochemistry International. - 2018. - Vol.56. - Iss. 4. - P.344-361. - ISSN 0016-7029. - EISSN 1531-8397.
Идентиф-ры:	DOI: 10.1134/S0016702918040043; РИНЦ: 35519284; РИНЦ: 35519284; SCOPUS: 2-s2.0-85045246812; WoS: 000429237200006;
Реферат:	eng: Organogenic sediments (sapropels) in lakes are characterized by a reduced type of diagenesis, during which organic compounds are decomposed, the chemical composition of the pore waters is modified, and authigenic minerals (first of all, pyrite) are formed. Pyrolysis data indicate that organic matter undergoes radical transformatons already in the uppermost sapropel layers, and the composition of this organic matter is principally different from the composition of the organic matter of the its producers. The sapropels contain kerogen, whose macromolecular structure starts to develop during the very early stages of diagenesis, in the horizon of unconsolidated sediment (0-5 cm). The main role in the diagenetic transformations of organic matter in sediments is played by various physiological groups of microorganisms, first of all, heterotrophic, which amonifying, and sulfate-reducing bacteria. SO42- and Fe2+ concentrations in the pore waters of the sediments are determined to decrease (because of bacterial sulfate reduction), while concentrations of reduced Fe and S species (pyrite) in the solid phase of the sediment, conversely, increase. Comparative analysis shows that, unlike sapropels in lakes in the Baikal area, sapropels in southern West Siberia are affected by more active sulfate reduction, which can depend on both the composition of the organic matter and the SO42- concentration in the pore waters.
Ключевые слова:	TRANSFORMATION; SEA; BOTTOM SEDIMENTS; FRAMBOIDAL PYRITE; ORGANIC-MATTER; pore waters; sulfate reduction; organic matter; diagenesis; geochemistry; SAPROPEL FORMATION; ORIGIN;
Издано:	2018
Физ. хар-ка:	с.344-361
Цитирование:	1. V. E. Artem’ev, Geochemistry of Organic Matter in the River–Sea System (Nauka, Moscow, 1993) [in Russian]. 2. M. M. Astafieva, A. Yu. Rozanov, and R. Hoover, “Framboids: their structure and origin,” Paleontol. J. 39 (5), 457–464 (2005). 3. Baikal Atlas, Ed. by G. I. Galaziya (Roskartografiya, Moscow, 1993) [in Russian]. 4. J. W. Ball and D. K. Nordstrom, “User’s manual for WATERQ4F, with revised thermodynamic date base and rest cases for calculating speciation of major, trace, and redox elements in natural waters,” (MenloPark, 1991). 5. N. A. Belkina, Extended Abstract of Candidate’s Dissertation in Geography (St. Petersburg, 2003) [in Russian]. 6. A. A. Bogush and E. V. Lazareva, “Behavior of heavy metals in sulfide mine and botton sediment Salair, Kemerovo region, Russia,” Environ. Earth Sci. 64 (5), 1293–1302 (2011). 7. A. J. Criddle, “A preliminary description of microcrystalline pyrite from the nannoplankton ooze at site 251, Southwest Indian ocean,” Initial Reports of the Deep Sea Drilling Project. Washington 26, 603–611 (1974). 8. L. L. Demina, D. F. Bud’ko, T. N. Alekseeva, A. N. Novigatsky, A. S. Filippov and A. I. Kochenkova, “Partitioning of trace elements in the process of early diagenesis of bottom sediments in the White Sea,” Geochem. Int., 55 (1), 144–150 (2017). 9. V. P. Fadeeva, V. D. Tikhova, and O. N. Nikulicheva, “Elemental analysis of organic compounds with the use of automated CHNS Analyzers,” J. Anal. Chem. 63 (11), 1094–1106 (2008). 10. R. L. Folk, “Nannobacteria and the formation of framboidal pyrite: textural evidence,” J. Earth Syst. Sci. 114 (3), 369–74 (2005). 11. Geochemistry of Diagenesis of Pacific Sediments (Transoceanic Profile), Ed. by E. A. Ostroumov (Nauka, Moscow, 1980) [in Russian]. 12. L. Z. Granina, Early Diagenesis of Sediments of Lake Baikal (Geo, Novosibirsk, 2008) [in Russian]. 13. Yu. N. Gurskii, Geochemistry of Lithohydrosphere of Internal Seas. Volume 2. Mud Waters of the Red and Mediterranean Seas. Estuarine Zones. Tendencies in the Formation and Classification of Waters of Lithohydrosphere (GEOS, Moscow, 2007) [in Russian]. 14. I. K. Karpov, K. V. Chudnenko, D. A. Kulik and V. A. Bychinskii, “The convex programming minimization of five thermodynamic potentials other than Gibbs energy in geochemical modeling,” Am. J. Sci. 302 (4), 281–311 (2002). 15. A. V. Karyakin and I. F Gribovskaya, Emission Spectral Analysis of Biosphere Objects (Nauka, Moscow, 1979) [in Russian]. 16. T. V. Khodzher, Extended Abstract of Candidate’s Dissertation in Geography (Moscow, 2005) [in Russian]. 17. V. N. Kholodov, Geochemistry of Sedimentary Process (GEOS, Moscow, 2006) [in Russian]. 18. Klemt, E. S. Kaminski, R. Miller, G. Zibold, M. Astner, M. Burger, and E. Schmid, “Normierung von Extraktionsexperimenten zur Bestimmung der Bindung von Radiocaesium an Sedimente des Luganersees,” Umweltradioaktivität und Strahlendosen in der Schweiz. Bundesamt für Gesundheit B. 4.4, 1–5 (2000). 19. M. J. Kohn, L. R. Riciputy, and D. L. Orange, “Sulfur isotope variability in biogenic pyrite: Reflections of heterogeneous bacterial colonization?,” Am. Mineral. 83, 1454–468 (1998). 20. N. M. Kokryatskaya, S. A. Zabelina, A. S. Savvichev, O. Yu. Moreva, and T. Ya. Vorobjeva, “Seasonal biogeochemical and microbiological studies of small lakes in taiga zone of northwestern Russian (Arkhangelsk Province),” Water Res. 39 (1), 105–117 (2012). 21. N. V. Korde, Biostratification and Typology of Russian Sapropels (AN SSSR, Moscow, 1960) [in Russian]. 22. E. V. Lazareva, G. A. Leonova, V. A. Bobrov, and L. V. Miroshnichenko, “Mineral composition and geochemistry of Holocene sapropel sequence of Lake Minzelinskoe (Novosobirsk oblast).” Geol. Mineral. Syr’ev. Res. Sibiri, No. 2, 118–122 (2014b). 23. A. Yu. Lein, Yu. M. Miller, B. B. Namsaraev, G. A. Pavlova, N. V. Pimenov, I. I. Rusanov, A. S. Savvichev, and M. V. Ivanov, “Biogeochemical processes of sulfur cycle at the early diagenetic stages of sediments on the Yenisei River–Kara Sea profile,” Okeanologiya 34 (5), 681–692 (1994). 24. A. Yu. Lein, N. A. Belyaev, M. D. Kravchishina, A. S. Savvichev, M. V. Ivanov, and A. P. Lisitsyn, “Isotopic markers of organic matter transformation at the water–sediment geochemical boundary,” Dokl. Earth Sci. 436 (2), 83–87 (2011). 25. G. A. Leonova, V. A. Bobrov, A. A. Bogush, and A. E. Mal’tsev, “Sapropels: wealth from the lake floor,” Nauka v Rossii 1, 28–35. (2014) 26. G. A. Leonova, V. A. Bobrov, S. K. Krivonogov, A. A. Bogush, V. A. Bychinskii, A. E. Mal’tsev, and G. N. Anoshink, “Biogeochemical specifics of sapropel formation in cisbaikalian undrained lakes (by the example of lake ochki),” Russ. Geol. Geophys. 56 (5), 745–761 (2015). 27. A. P. Lisitzin, “Distribution of organic carbon in sediments of the Bering Sea,” Dokl. Akad. Nauk SSSR 103 (2), 299–302 (1955). 28. N. V. Logvinenko, Marine Geology (Nedra, Leningrad, 1980) [in Russian]. 29. K. I. Lukashev, V. A. Kovalev, A. L. Zhukhovitskaya, A. A. Khomich, and V. A. Generalova, Geochemistry of Lacrustrine–Marsh Lithogenesis (Nauka Tekhnika, Minsk, 1971) [in Russian]. 30. A. E. Mal’tsev, G. A. Leonova, L. V. Miroshnichenko, V. A. Bobrov, A. A. Bogush, and S. K. Krivonogov, “Mineral composition of planktonogenic sapropel of Lake Kotokel (Baikal region), Geology of Seas and Oceans. Proceedings of 21 st International Conference (School) on Marine Geology (GEOS, Moscow, 2015), Vol. 3, 56–59 [in Russian]. 31. A. E. Mal’tsev, G. A. Leonova, V. A. Bobrov, V. N. Melenevskii, E. V. Lazareva, and S. K. Krivonogov, “Diagenetic transformation of organomineral sapropels of Lake Bol’shie Toroki, West Siberia,” Geol. Mineral. Res. Sibiri 3 (19), 65–75 (2014a). 32. Manual on the Chemical Analysis of Terrestrial Surface Waters, Ed. by A. D. Semenov (Gidrometeoizdat, Leningrad, 1977) [in Russian]. 33. Mass Concentration of Hydrocarbonates and Alkalinity of Terrestrial Surface Waters and Purified Sewage Waters. Technique of Titration Measurements (Rostov on Don, 2006), RD 52.24.493-2006t [in Russian]. 34. V. N. Melenevsky, G. A. Leonova, and A. S. Konyshev, “The organic matter of the recent sediments of Lake Beloe (West Siberia) (from data of pyrolytic studies),” Russ. Geol. Geophys. 52 (6), 583–592 (2011). 35. V. N. Melenevsky, S. V. Saraev, E. A. Kostyreva, and V. A. Kashirtsev, “Diagenetic transformation of organic matter of the Holocene Black Sea sediments according to pyrolysis data,” Russ. Geol. Geophys. 58 (2), 225–239289 (2017). 36. Method of Argentometric Measurement of Chloride Mass Concentrations in Samples of Natural and Purified Sewage Waters (Rostov on Don, 2004) [in Russian]. 37. Method of Turbidimetric Measurement of Sulfate-Ion Mass Concentrations in Samples of Natural and Purified Sewage Waters (Rostov on Don, 2005) [in Russian]. 38. B. B. Namsaraev and T. I. Zemskaya, Microbiological processes of carbon cycle in the bottom sediments of Lake Baikal (GEO, Novosibirsk, 2000) [in Russian]. 39. Organomineral Agricultural Raw Material of the Novosibirsk Oblast (Novosibirsk, 1990) [in Russian]. 40. T. V. Pogodaeva, T. I. Zemskaya, L. P. Golobokova, O. M. Khlystov, H. Minami, and H. Sakagami, “Chemical composition of pore waters of bottom sediments in different Baikal basins,” Russ. Geol. Geophys. 48 (11), 886–900 (2007). 41. E. A. Romankevich, Geochemistry of Organic Matter in Ocean (Nauka, Moscow, 1977) [in Russian]. 42. A. G. Rozanov, I. V. Volkov, V. S. Sokolov, Z.V. Pushkina, and M. F. Pilipchuk, “Redox processes in sediments of Californian Bay and adjacent Pacific Ocean, Biogeochemistry of Diagenesis of Oceanic Sediments (Nauka, Moscow, 1976) [in Russian]. 43. D. N. Salikhov, G. I. Belikova, and E V. Sergeeva, “Equilibrium thermodynamics of ore manganese minerals,” Geol. Sb. 9, 164–172 (2011). 44. A. V. Savenko, “Solubility of rhodochrosite MnCO3 and physicochemical stage of manganese (II) in seawater,” Proceedings of Annual Seminar on Experimental Mineralogy, Petrology, and Geochemistry, Moscow, Russia, 2004 (GEOKHI, Moscow, 2004) [in Russian]. 45. O. V. Shishkina, Geochemistry of Marine and Oceanic Mud Waters (Nauka, Moscow, 1972) [in Russian]. 46. V. I. Simonova, Atomic Absorption Methods of Element Determination in Rocks and Minerals (Nauka, Novosibirsk, 1986) [in Russian]. 47. B. A. Skopintsev, “Organic matter in bottom waters,” Tr. GOIN 17 (29), (1950). 48. M. F. Soliman and A. El Goresy, “Framboidal and idiomorphic pyrite in the upper Maastrichtian sedimentary rocks at Gabal Oweina, Nile Valley, Egypt: formation processes, oxidation products and genetic implications to the origin of framboidal pyrite,” Geochim. Cosmochim. Acta 90, 195–200 (2012). 49. N. M. Strakhov, “Diagenesis of sediments and its significance for sedimentary ore formation,” Izv. Akad. Nauk SSSR. Ser. Geol., No. 5, 12–49 (1953). 50. A. P. Tessier, G. C. Cambell, and M. Bisson, “Sequential extraction procedure for the speciation of particulate trace metals,” Anal. Chem. 51, 844–851 (1979). 51. K. V. Titova and N. M. Kokryatskaya, “Sulfate reduction in bottom sediments of Lake Svyatoe (southern Arkhangelsk oblast),” Vestn. Irkut. Gos. Tekhn Univ., Nauki Zemle 84 (1), 52–56 (2014). 52. P. A. Trudinger, I. B. Lambert, and G. W. Skyring, “Biogenic sulfide ores: a feasibility study,” Econ. Geol. 67 (8), 1114–1127 (1972). 53. I. I. Volkov, Sulfur Geochemistry in Ocean Sediments (Nauka, Moscow, 1984) [in Russian]. 54. L. A. Vorob’eva, Chemical Analysis of Soils. A Textbook (Mosk. Gos. Univ., Moscow, 1998) [in Russian]. 55. K. K. Votintsev, Hydrochemistry of Lake Baikal (Nauka, Moscow, 1961) [in Russian]. 56. N. I. Yermolaeva, E. Yu. Zarubina, R. E. Romanov, G. A. Leonova, and A. V. Puzanov, “Hydrobiological conditions of sapropel formation in lakes in the south of Western Siberia,” Water Res. 43 (1), 129–140 (2016). 57. Ya. E. Yudovich and M. P. Ketris, Geochemical Indicators of Lithogenesis (Lithological Geochemistry) (Geoprint, Syltyvkar, 2011) [in Russian]. 58. E. Yu. Zarubina, “Primary production of macrophytes of three sapropel lakes of different types, southern West Siberia (Novosibirsk oblast) in 2012,” Mir Nauki, Kul’tury, Obrazovaniya 5 (42), 441–444 (2013). 59. Ya. E. Yudovich and M. P. Ketris, Manganese Geochemistry (Geoprint, Syktyvkar, 2014) [in Russian].